When a proton encounters its antiparticle (and more generally, if any species of baryon encounters any species of antibaryon), the reaction is not as simple as electron-positron annihilation. Unlike an electron, a proton is a composite particle consisting of three "valence quarks" and an indeterminate number of "sea quarks" bound by gluons. Thus, when a proton encounters an antiproton, one of its constituent valence quarks may annihilate with an antiquark, while the remaining quarks and antiquarks will undergo rearrangement into a number of mesons (mostly pions and kaons), which will fly away from the annihilation point. The newly created mesons are unstable, and will decay in a series of reactions that ultimately produce nothing but gamma rays, electrons, positrons, and neutrinos. This type of reaction will occur between any baryon (particle consisting of three quarks) and any antibaryon (consisting of three antiquarks). Antiprotons can and do annihilate with neutrons, and likewise antineutrons can annihilate with protons.
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