The relative proportion of 13C in our atmosphere is steadily decreasing over time. Before the industrial revolution, d13C of our atmosphere was approximately -6.5‰; now the value is around -8‰. Recall that plants have less 13C relative to the atmosphere (and therefore have a more negative d13C value of around -25‰). Most fossil fuels, like oil and coal, which are ancient plant and animal material, have the same d13C isotopic fingerprint as other plants. The annual trend–the overall decrease in atmospheric d13C–is explained by the addition of carbon dioxide to the atmosphere that must come from the terrestrial biosphere and/or fossil fuels. In fact, we know from D14C measurements, inventories, and other sources, that this decrease is from fossil fuel emissions, and is an example of the Suess Effect.
Recall that the Suess Effect is the observed decrease in d13C and D14C values due to fossil fuel emissions, which are depleted in 13C and do not contain 14C.
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